Carbon Compounds Ethanol And Ethanoic Acid

In a region, total annual consumption of gasoline is 30.6 million tons. The land required for growing sugarcane to produce enough bioethanol to replace the gasoline completely is ___________ (an integer value).
Ethanol energy equivalent is 67% of gasoline, gasoline density is 850 , yield of bioethanol produced from sugarcane per hectare of land is 3750 L, and 1 = 100 hectares

Initially a bottle contained 400 g of ethanol. Half of ethanol was used by a student for preparing the stock solution in an environmental chemistry laboratory just before summer vacation of 90 days. After completing the procedure, the student left the bottle uncorked. If the unsealed bottle losses ethanol at a rate of 0.5 g/day, the ethanol that will be left in the bottle at the end of the summer vacation is __________ g (an integer value).