will be .It is the ozonolysis reaction of alkyne that produces directly followed by reductive cleavage with dust.
02
PYQ 2016
easy
chemistryID: bitsat-2
The compounds and , respectively are
1
cis-butene-2 and rac-2, 3-dideuterobutane
2
trans-butene-2 and rac-2, 3-dideuterobutane
3
cis-butene-2 and meso-2, 3-dideuterobutane
4
trans-butene-2 and meso-2, 3-dideuterobutane
Official Solution
Correct Option: (3)
. Alkynes are catalytically hydrogenated to produce cis-alkene, which is then further hydrogenated in the presence of platinum to produce meso-2,3-dideuterobutane. The conversion of is the net response of Cā”C to C-C with the addition of two molecules of H2 and D2
Alkynes may be hydrogenated by simply adding hydrogen atoms across their triple bonds. Alkane results from the formation of a carbon-carbon double bond, while alkene results from the formation of a carbon-carbon single bond.
A bond will be lost if hydrogen atoms are added across a double bond.
The result of hydrogenating the provided alkyne is
Furthermore, the double bond in cis-2-butene is broken down into a single bond and an alkane is produced when deuterium is added in the presence of a platinum catalyst.
Meso compounds are substances that contain a centre of symmetry and are optically active, meaning they exhibit a non-superimposable mirror image.
A racemic mixture is a collection of substances with both a (R) and a (S) structure.
The compound produced cannot be a racemic combination because it displays optical activity.
The resultant product is a meso compound in this case because it possesses a plane of symmetry and a non-superimposable mirror image that makes it optically active
So, the correct answer is cis-butene-2 and meso-2,3-dideuterobutane.