NEET
Chemistry

Electron Affinity Ea

Low Priority
Consistency: 10%
Weightage: 2 / 20 Yrs

High-Yield Trend

1
2015
1
2010

Questions
2 MCQs

01
PYQ 2010
easy
chemistry ID: neet-201

The correct order of increasing electron affinity for the elements, O, S, F and Cl is:

1. Cl < F < O < S 2. O < S < F < Cl
3. F < S < O < Cl 4. S < O < Cl < F
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02
PYQ 2015
easy
chemistry ID: neet-201

The formation of the oxide ion O2– (g), from the oxygen atom requires first an exothermic and then an endothermic step as shown below,
Og+e-O-; fH0=141 kJ mol-1
O-g+e-O2-g; fH0=+780 kJ mol-1

Thus, the process of formation of O2– in the gas phase is unfavorable even though O2– is isoelectronic with neon. It is due to the fact that:

1. Electron repulsion outweighs the stability gained by achieving noble gas configuration.
2. O ion has a comparatively smaller size than the oxygen atom.
3. Oxygen is more electronegative.
4. Addition of electrons in oxygen results in a large size of the ion.
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