Nomenclature Of Coordination Compounds

The given complex is , which is made up of two parts:
The first part involves a platinum (II) ion coordinated to four ammine ( ) ligands. The ammine is neutral and the platinum is in the oxidation state.
The second part involves a platinum ion coordinated to four chloride ( ) ligands, where platinum is in the oxidation state.
Thus, the correct IUPAC name involves: The first part, , is named "tetra ammine platinate (0)" since platinum is in the oxidation state, making it a platinate (0) complex. - The second part, , is named "tetra chlorido platinum (IV)" since platinum is in the oxidation state.

Thus, the IUPAC name is "tetra ammine platinate (0) tetra chlorido platinum (IV)".

1. K3[Al(C2O4)3] - Potassium trioxalatoaluminate (III)

• The formula is correct.
• The name is correct. C2O4 is oxalate, and it's a tridentate ligand. Al has a +3 oxidation state.

2. [Pt(NH3)2 Cl(NO2)]- Diamminechloridonitrito - N - platinum (II)

• The formula is correct.
• The name is correct. NH3 is ammine, Cl is chlorido, NO2 is nitrito-N, and Pt has a +2 oxidation state.

3. [CoCl2(en)2]Cl - Dichloridodiethylenediammine cobalt (II) chloride

• This formula and name combination is INCORRECT.
• The correct name should be: Dichloridobis(ethylenediamine)cobalt(III) chloride.
  • 'en' is ethylenediamine, which is a neutral bidentate ligand.
  • The oxidation state of Co is +3, not +2.
  • The prefix 'bis' is used for bidentate ligands.

4. [Co(NH3)4 (H2O)Cl]Cl2 - Tetraammineaquachloridocobalt (III) chloride

• The formula is correct.
• The name is correct. NH3 is ammine, H2O is aqua, Cl is chlorido, and Co has a +3 oxidation state.

Conclusion:

The incorrect formula and name combination is Option 3.

The correct answer is Option 3.