AP-EAPCET SERIES
Chemistry

Solutions

32 previous year questions.

Volume: 32 Ques
Yield: High

High-Yield Trend

13
2025
2
2024
7
2023
10
2022

Chapter Questions
32 MCQs

01
PYQ 2022
medium
chemistry ID: ap-eapce
At T (K), x g of a non-volatile solid (molar mass 78 g mol ) when added to 0.5 kg water, lowered its freezing point by 1.0°C. What is x (in g)? (K of water at T(K) = 1.86 K kg mol )
1
10.48
2
20.96
3
41.92
4
5.24
02
PYQ 2022
medium
chemistry ID: ap-eapce
Assertion (A): MgSO4 is readily soluble in water.
Reason (R): The greater hydration enthalpy of Mg2+ ions overcomes its lattice enthalpy.
1
A and R both are correct and R is the correct explanation of A.
2
A and R both are correct but R is not the correct explanation of A.
3
A is correct but R is not correct
4
A is incorrect but R is correct
03
PYQ 2022
medium
chemistry ID: ap-eapce

Which of the following are extensive properties?

1

A, B, C and E

2

A, B, and D

3

A, B, and D

4

A, B, E only

04
PYQ 2022
medium
chemistry ID: ap-eapce
For which of the following liquid mixtures and ?}
1
ethyl chloride, ethyl bromide
2
ethanol, acetone
3
phenol, aniline
4
chloroform, acetone
05
PYQ 2022
medium
chemistry ID: ap-eapce
Which of the following compounds do not have sp carbon atom(s)?
I. Acetone\quad II. Acetic acid\quad III. Buta-1,3-diene\quad IV. Propyne\quad V. Naphthalene
1
I only
2
II, III only
3
IV, V only
4
III, V only
06
PYQ 2022
medium
chemistry ID: ap-eapce
3.1 g of a compound, 'X' (molar mass = 62 g mol ) is dissolved in 19.5 g of other compound, Y (molar mass = 78 g mol ). The ratio of mole fractions of X and Y in the solution is
1
1:5
2
5:1
3
4:1
4
1:4
07
PYQ 2022
medium
chemistry ID: ap-eapce
A solution containing 6.0 g of urea is isotonic with a solution containing 10 g of a non-electrolytic solute X. The molar mass of X (in g mol\textsuperscript{-1}) is
1
50.0
2
100
3
75.0
4
68.0
08
PYQ 2022
medium
chemistry ID: ap-eapce
The pair of elements that form both oxides and nitrides, when burnt in air are
1
Na, Mg
2
Na, Be
3
Mg, Ca
4
Be, Mn
09
PYQ 2022
medium
chemistry ID: ap-eapce
Which of the following form an ideal solution?
1
Chloroethane and bromoethane
2
I \& II only
3
II \& III only
4
II, III \& IV only
10
PYQ 2022
medium
chemistry ID: ap-eapce
50 g of a substance is dissolved in 1 kg of water at . When the temperature is lowered to , the density increases from to . What is the percentage change in molarity of the solution?
1
10
2
4.5
3
5
4
7.3
11
PYQ 2023
medium
chemistry ID: ap-eapce
1.06 g of Na CO (molar mass = 106 g mol ) is dissolved in 500 g water. What is its molality?
1
0.2 m
2
0.02 m
3
2 m
4
0.04 m
12
PYQ 2023
medium
chemistry ID: ap-eapce

Match the following:

PropertyExpression
A. πI. Kb · m
B. ΔTfII. Kf · m
C. ΔTbIII. CST
D. (P0 - P) / P0IV. (n1 / (n1 + n2))
1
A – III, B – II, C – I, D – IV
2
A – IV, B – II, C – I, D – III
3
A – II, B – I, C – IV, D – I
4
A – I, B – III, C – II, D – IV
13
PYQ 2023
medium
chemistry ID: ap-eapce
The number of moles of OH ions present in 100 mL of 0.2 M Al(OH) solution is (assume 100% dissociation)
1

2

3

4

14
PYQ 2023
medium
chemistry ID: ap-eapce
34.2% (W/V) sucrose solution is isotonic with 18% (W/V) of unknown solution X. Formula of X is
1

2

3

4

15
PYQ 2023
medium
chemistry ID: ap-eapce
Which of the following in not correct?
1
n-hexane + n-heptane - Ideal solution
2
C H OH + H O - Positive deviation from Raoult's Law
3

4

16
PYQ 2023
medium
chemistry ID: ap-eapce
An example of a network solid is:
1

2

3

4

17
PYQ 2023
medium
chemistry ID: ap-eapce
Which of the following does not belong to an ideal solution?
1
2
3
Obeys Raoult's law over the entire range of concentration
4
Does not obey Raoult's law
18
PYQ 2024
easy
chemistry ID: ap-eapce

Aqueous CuSO4 solution was electrolysed by passing 2 amp of current for 10 min. What is the weight (in g) of copper deposited at cathode? (Cu = 63 u; F = 96500 C mol-1)

1
0.195
2
0.39
3
0.78
4
1.57
19
PYQ 2024
medium
chemistry ID: ap-eapce

Evaluate the correctness of the given statements.
I. Negative deviation occurs when A-B interactions are stronger than A-A and B-B.
II. Reverse osmosis requires applied pressure greater than osmotic pressure.

1
Both Statement-I and Statement-II are correct
2
Both Statement-I and Statement-II are incorrect
3
Statement-I is correct but Statement-II is not correct
4
Statement-I is not correct but Statement-II is correct
20
PYQ 2025
medium
chemistry ID: ap-eapce
A liquid mixture of aniline and 'x' forms a non-ideal solution with negative deviation from Raoult's law. What is 'x'?
1
Benzene
2
Acetone
3
Phenol
4
Toluene
21
PYQ 2025
easy
chemistry ID: ap-eapce
Calculate the molality of a solution prepared by dissolving 10 g of NaCl ( ) in 500 g of water:
1
0.171 mol/kg
2
0.342 mol/kg
3
0.017 mol/kg
4
0.34 mol/kg
22
PYQ 2025
easy
chemistry ID: ap-eapce

Calculate the boiling point of a solution containing 18 g of glucose (C H O ) in 100 g of water. (K₋b = 0.52°C·kg/mol, Molar mass of glucose = 180 g/mol)

1
100.52°C
2
100.26°C
3
100.13°C
4
101.00°C
23
PYQ 2025
medium
chemistry ID: ap-eapce
In an aqueous glucose solution, the mole fraction of water is 40 times the mole fraction of glucose. What is the weight percentage (w/w) of glucose in the solution?
1

2

3

4
24
PYQ 2025
hard
chemistry ID: ap-eapce

What is the molarity of a solution prepared by dissolving 5.85 g of NaCl in 500 mL of water?
(Molar mass of NaCl = 58.5 g/mol)

1
0.1 M
2
0.2 M
3
1.0 M
4
2.0 M
25
PYQ 2025
medium
chemistry ID: ap-eapce
Benzoic acid molecules undergo dimerisation in benzene. 2.44 g of benzoic acid when dissolved in 30 g of benzene caused depression in freezing point of 2 K. What is the percentage of association of it ? (Given ; molar mass of benzoic acid )
1

20

2

70

3

60

4

90

26
PYQ 2025
medium
chemistry ID: ap-eapce
What are the mole fractions of glucose and water respectively, in 20% (w/w) aqueous glucose solution? ( ; ; )
1
0.0244, 0.9756
2
0.04, 0.96
3
0.0636, 0.9364
4
0.0124, 0.9876
27
PYQ 2025
medium
chemistry ID: ap-eapce
The osmotic pressure of 0.01 molar solution of an electrolyte is found to be 0.65 bar at 27°C. The van’t Hoff factor of the electrolyte is (R = 0.083 bar L K mol )
1
2.610
2
1.610
3
2.305
4
1.805
28
PYQ 2025
medium
chemistry ID: ap-eapce

At 298 K, liquid A (solute) forms an ideal solution with liquid B (solvent). The following graph is obtained for this solution.

Identify the correct statements about this graph:
I) x-axis represents the mole fraction of A
II) Point Z represents the vapour pressure of pure solvent
III) x-axis represents the mole fraction of B

1
I only
2
II only
3
II, III only
4
I, II, III
29
PYQ 2025
medium
chemistry ID: ap-eapce
The mole fractions of glucose and water in aqueous glucose solution are 0.0244 and 0.9756 respectively. What is the weight percentage (w/w) of glucose in this solution?
1
40
2
25
3
20
4
10
30
PYQ 2025
medium
chemistry ID: ap-eapce
At T(K), the vapour pressure of an aqueous solution of a non-volatile solute,
whose mole fraction is 0.02 is found to be 34.65 mm Hg.
What is the vapour pressure (in mm Hg) of pure water at the same temperature?
1
35.70
2
35.36
3
35.00
4
34.30
31
PYQ 2025
medium
chemistry ID: ap-eapce
Consider the following:
Assertion (A): Nitric acid - water mixture is a maximum boiling azeotrope.
Reason (R): Nitric acid - water mixture shows positive deviation from Raoult’s law.
1
Both (A) and (R) are correct and (R) is the correct explanation of (A)
2
Both (A) and (R) are correct but (R) is not the correct explanation of (A)
3
(A) is correct, but (R) is not correct
4
(A) is not correct, but (R) is correct
32
PYQ 2025
medium
chemistry ID: ap-eapce
Two acids A and B are titrated separately. 25 mL of 0.5 M Na CO solution requires 10 mL of A and 40 mL of B for complete neutralisation. The volume (in L) of A and B required to produce 1 L of 1 N acid solution respectively are
1
0.2, 0.8
2
0.8, 0.2
3
0.3, 0.7
4
0.7, 0.3